1-Methyl-3-(3-oxocyclohex-1-enyl)azepan-2-one

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1-Methyl-3-(3-oxocyclo­hex-1-en­yl)azepan-2-one

The title compound, C(13)H(19)NO(2), is a inter-mediate in the synthesis of the opioid analgesic meptazinol. In the crystal structure, a weak inter-molecular C-H⋯O inter-action occurs.

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The asymmetric unit of the title compound, C(21)H(26)O(4)S, consists of two independent mol-ecules. In both mol-ecules, intra-molecular O-H⋯O hydrogen bonds stabilize the mol-ecular structure. In the crystal, each mol-ecule and its symmetry-related mol-ecule by twofold rotation form a dimer through a pair of inter-molecular C-H⋯O hydrogen bonds. In one of the mol-ecules, the thio-phene group is...

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1-Methyl-3-phenyl­quinoxalin-2(1H)-one

The phenyl substituents in both independent mol-ecules of the title compound, C(15)H(12)N(2)O, are twisted with respect to the quinoxaline system [dihedral angles = 19.3 (1) and 30.4 (1)°].

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3-Methyl-1-propargylquinoxalin-2(1H)-one

The ten-membered fused ring of the title compound, C(12)H(10)N(2)O, is essentially planar in the two independent mol-ecules of the asymmetric unit (r.m.s. deviations = 0.012 and 0.015 Å).

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(2E)-3-(2-Chloro-6-methyl-3-quinol­yl)-1-(1-naphth­yl)prop-2-en-1-one

In the title mol-ecule, C(23)H(16)ClNO, the quinoline and naphthalene ring systems are individually planar, with maximum deviations of 0.020 (2) and 0.033 (2) Å, respectively, and are inclined at a dihedral angle of 30.01 (4)°. Intra-molecular C-H⋯O and C-H⋯Cl inter-actions occur. The crystal structure is devoid of any classical hydrogen bonds, but symmetry-related mol-ecules are linked via wea...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s160053680802895x